教授 –孙松
Email: sunsong@cczu.edu.cn
教育经历:
2019年9月-2020年9月 香港科技大学,访问学者
2004年9月-2008年6月,江苏工业学院 学士
2009年9月-2013年6月,苏州大学 博士
工作经历:
2014年3月-至今,新浦京8883平台
个人荣誉:
2019年度新浦京8883平台“第六届我最喜欢的教师”
2021年新浦京8883平台优秀硕士毕业论文指导老师
常州市第十六次“自然科学优秀科技论文”三等奖,2021年
社会兼职(社会兼职填是否担任过专业杂志编委、专业委员会委员、专业协会会员等)
中国化学会,会员
研究方向:
二氧化碳固定转化,有机合成方法学
教学科研项目:
国家自然科学基金青年项目,以二氧化碳为羰基源/两性离子为关键中间体构建含羰基杂环化合物的反应研究、20万元、项目负责人。
江苏省自然科学基金青年项目,新型阳离子型稀土金属胺基配合物的合成、表征及催化烯烃、炔烃分子间氢胺化反应研究、20万元、项目负责人。
发改委“环保功能吸附材料制备技术国地联合工程实验室”开放研究课题,以工业废气“CO2”为C1源的羧基化反应研究,5万元、项目负责人
发表论文
Wanxu Gao, Qi Yang, Han Yang, Yang Yao, Junxue Bai, Jianwei Sun, and Song Sun*, Visible-Light Photoredox-Catalyzed Intermolecular α-Aminomethyl/Carboxylative Dearomatization of Indoles with CO2 andα-Aminoalkyl Radical Precursors, Org. Lett. 2024, 26, 467−472.
Qi Yang, Junxue Bai, Han Yang, Yang Yao, Yingming Yao, Jianwei Sun, and Song Sun*, [Cp*IrCl2]2 Catalyzed Amidocarbonation of Olefins with Sulfoxonium Ylides toward Functionalized Isoindolin-1-ones, Org. Lett. 2023, 25, 7148−7153.
Yu Sha, Junxue Bai, Miao Li, Wanxu Gao, Qi Yang, Jianwei Sun, and Song Sun*, Base-Promoted 5-exo-dig Cyclization of o-Alkynylamides or 2-En-4-ynamides with CO2 toward Fully Substituted Acrylates, Org. Lett.2022, 24, 5715−5720.
Miao Li, Yaqun Dong, Cong Zhou, Junxue Bai, Jiang Cheng, Jianwei Sun, and Song Sun*, Iridium-Catalyzed Redox-Neutral C2 and C3 Dual C−HFunctionalization of Indoles with Nitrones toward7H Indolo[2,3 c]quinolones, Org. Lett.2021, 23, 8229−8234.
Cong Zhou, Miao Li, Jianwei Sun, Jiang Cheng,* and Song Sun*, Photoredox-Catalyzed α-Aminomethyl Carboxylation of Styreneswith Sodium Glycinates: Synthesis of γ-Amino Acids and γ-Lactams, Org. Lett.2021, 23, 2895−2899.
Junxue Bai, Miao Li, Cong Zhou, Yu Sha, Jiang Cheng, Jianwei Sun, and Song Sun*, Visible-Light Photoredox-Catalyzed Dicarbofunctionalization ofStyrenes with Oxime Esters and CO2: Multicomponent Reactionstoward Cyanocarboxylic Acids and γ Keto Acids, Org. Lett.2021, 23, 9654−9658.
Song Sun, Zhaobin Wang, Shijia Li, Cong Zhou, Lijuan Song, Hai Huang*, and Jianwei Sun*, An Organocatalytic Kinetic Resolution of Aziridines by Thiol Nucleophiles, Org. Lett.2021, 23, 2, 554–558.
Hui Qian,‡Song Sun,‡ Wanxiang Zhao, Jianwei Sun*, An efficient [3+2] annulation for the asymmetricsynthesis of densely-functionalized pyrrolidinonesand γ-butenolides, Chem. Commun.2020, 56, 11295−11298.
Cong Zhou,Miao Li, Jin-Tao Yu, Song Sun*,Jiang Cheng*, Recent Progress in the Carboxylation/Cyclization Reactions Using Carbon Dioxide as the C1 Source, Chin. J. Org. Chem.2020, 40, 2221-2231.
Cong Zhou, Yaqun Dong, Jin-Tao Yu, Song Sun* and Jiang Cheng*, Palladium/Copper-Catalyzed Multicomponent Reactions of Propargylic Amides, Halohydrocarbon and CO2 toward 5-Benzylidene Oxazolidine-2,4-diones, Chem. Commun. 2019, 55, 13685−13688.
Shengbo Xu, Jiangang Teng, Jin-Tao Yu, Song Sun*and Jiang Cheng*, Copper-Mediated Direct Cyanation of Heteroarenes and Arenes C–H Bondsby the Combination of Ammonium and DMF, Org. Lett.2019, 21, 9919−9923.
Shengnan Jin, Song Sun, Jin-Tao Yu, and Jiang Cheng*, The Silver-Promoted Phosphonation/Alkynylation of Alkene Pro-ceeding with Radical 1,2- Alkynyl Migration,J. Org. Chem.2019, 84, 11177−11185.
Song Sun, Cong Zhou, Jin-Tao Yu and Jiang Cheng*, Visible-Light-Driven Palladium-Catalyzed Oxy-Alkylation of 2-(1-Arylvinyl)anilines by Unactivated Alkyl Bromides and CO2: MCRs toward 1,4-Dihydro-2H-3,1-benzoxazin-2-ones, Org. Lett.2019, 21, 6579−6583.
Song Sun*, Cong Zhou, Jin-Tao Yu and Jiang Cheng*, Synthesis of 4-Cyanoethylated Benzoxazines by Visible-light-promoted Radical Oxycyanomethylation of Olefinic Amides with Bromoacetonitrile, Tetrahedron Lett.2019, 60, 150926-150930.
Yaqun Dong, Song Sun*, Jin-tao Yu, Jiang Cheng, Rhodium(III)-catalyzed direct C-7 sulfonamidation and amination ofindolines with arylsulfonamides and trifluoroacetamide, Tetrahedron Lett.2019, 60, 1349–1352.
Shengbo Xu, Shanshan Qiao, Song Sun*, Jin-Tao Yu and Jiang ChengRhodium-catalyzed C–H Activation/annulation of Amidines with 4-Diazoisochroman-3-iminestoward Isochromeno[3,4-c]isoquinolines, Org. Biomol. Chem.2019, 17, 8417–8424.
Yan Xiao, Xiaopeng Wu, Jiangang Teng, Song Sun*, Jin-Tao Yu andJiang Cheng, Copper-catalyzed Acylation of Pyrazolones with Aldehydes to afford 4-Acylpyrazolones, Org. Biomol. Chem. 2019, 17, 7552–7557.
Song Sun, Bingbing Wang, Ning Gu, Jin-Tao Yu and Jiang Cheng*, Palladium-Catalyzed Arylcarboxylation of Propargylic Alcohols with CO2 and Aryl Halides: Access to Functionalized α-Alkylidene Cyclic Carbonates, Org. Lett. 2017,19, 1088-1091.
Bingbing Wang, Song Sun, Jin-Tao Yu, Yan Jiang, and Jiang Cheng*, Palladium-Catalyzed Multicomponent Reactions of o Alkynylanilines,Aryl Iodides, and CO2 toward 3,3-Diaryl 2,4-Quinolinediones, Org. Lett.2017, 19, 4319−4322.
Song Sun, Wei-Ming Hu, Ning Gu, and Jiang Cheng*, Palladium-Catalyzed Multi-Component Reactions ofN-Tosylhydrazones, 2-Iodoanilines and CO2 towards4-Aryl-2-Quinolinones, Chem. Eur. J.2016, 22, 1-5. 18729-18732.
Song Sun, Jin-Tao Yu, Yan Jiang, and Jiang Cheng*, Cs2CO3 Promoted Carboxylation of N-Tosylhydrazones with Carbon Dioxide toward α-Arylacrylic Acids, J. Org. Chem.2015, 80, 2855−2860.
Song Sun, Jin-Tao Yu, Yan Jiang, and Jiang Cheng*, Copper(I)-Catalyzed Desulfinative Carboxylation of SodiumSulfinates using Carbon Dioxide, Adv. Synth. Catal.2015, 357, 2022–2026.
Song Sun, Kun Nie, Yufang Tan, Bei Zhao, Yong Zhang,Qi Shen, Yingming Yao,* Bimetallic lanthanide amido complexes as highly active initiators for the ring-opening polymerization of lactides, Dalton Trans. 2013,42, 2870-2878.
Song Sun, Qiu Sun, Bei Zhao, Yong Zhang,Qi Shen, and Yingming Yao,* Unexpected C-H Bond Activation Promoted by Bimetallic Lanthanide Amido Complexes Bearing a META-Phenylene Bridged Bis(β–diketiminate) Ligand, Organometallics2013,32, 1876-1881.
Song Sun, Hao Ouyang, Yunjie Luo,* Yingming Yao,* Yong Zhang, Qi Shen, Synthesis of β-diketiminate-ligated bimetallic and monometallic lanthanide amide complexes and their reactivity with isoprene and AlMe3,Dalton Trans. 2013, 42, 16355-16364.
授权专利
一种由二氧化碳制备芳基甲酸的方法,发明专利,授权号:ZL 201410337963.0
一种由二氧化碳制备4-芳基-2-喹啉酮的方法,发明专利,授权号:ZL 201610813950.5
孙松,成江,于金涛,顾宁,杨锐,一种由环醚类化合物制备2-芳基喹啉的方法,发明专利,授权号:ZL 201610263718.9
孙松,李渺,董亚群,孙建伟,周聪,6-苯基-7-(吡啶-2-基)-7H-吲哚并[2, 3-c]喹啉化合物的合成方法,2022年,中国发明专利,授权号:ZL202110589804.X